10061-02-6,Some common heterocyclic compound, 10061-02-6, name is trans-1,3-Dichloropropene, molecular formula is C3H4Cl2, traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.
General procedure: A mixture of 0.01 mol (1.0 g) of pentane-2,4-dione, 0.001 mol (0.1 g) of sodium butylate, and 60 mL of anhydrous acetonitrile was irradiated at constant stirring for 20 min. The mixture was then cooled to room temperature and was charged with 0.015 mol of the corresponding alkene 4. Next, irradiation was continued for 2 h to complete conversion of pentane-2,4-dione. Upon completion of the reaction (GLC monitoring) the mixture was cooled to room temperature, washed with water, and extracted with chloroform. The organiclayer was dried with potassium carbonate and evaporated. The residue was distilled in a vacuum.
These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route 10061-02-6, its application will become more common.
Reference:
Letter; Borisova, Yu. G.; Raskildina; Zlotskii; Russian Journal of General Chemistry; vol. 86; 9; (2016); p. 2126 – 2128; Zh. Obshch. Khim.; vol. 86; 9; (2016); p. 1564 – 1566,3;,
Chloride – Wikipedia,
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