Reference of 1005-56-7, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 1005-56-7, Name is O-Phenyl carbonochloridothioate, SMILES is S=C(Cl)OC1=CC=CC=C1, belongs to chlorides-buliding-blocks compound. In a article, author is Wei, Zhi-Quan, introduce new discover of the category.
Unexpected Boosted Solar Water Oxidation by Nonconjugated Polymer-Mediated Tandem Charge Transfer
Conjugated polymers are deemed as conductive carrier mediators for engendering the pi electrons along the molecular framework, while the role of nonconjugated insulated polymers has been generally overlooked without the capability to participate in the solar-powered oxidation-reduction kinetics and charge-transfer process. Alternatively, considering the ultrashort charge lifetime and significant deficiency of metal nanocluster (NC)-based photosystems, the fine tuning of charge migration over atomically precise ultrasmall metal NCs as novel light-harvesting antennas has so far not yet been unleashed. Here, we unlock the charge-transfer capability of a nonconjugated polymer to modulate the charge flow over metal NCs (Au-x and Au-25) by such a solid-state nonconductive polymer via a conceptually new chemistry strategy by which l-glutathione (GSH)-capped gold (Au-x@GSH) NCs and poly(diallyl-dimethylammonium chloride) (PDDA) were alternately self-assembled on the metal oxide (MO: WO3, Fe2O3, and TiO2) substrates. The ultrathin nonconjugated PDDA interim layer periodically intercalated in-between Au-x (Au-25) NC layers concurrently serves as an unexpected charge-transfer mediator to foster the unidirectional electron flow from Au-x(Au-25) NCs to MOs by forming a tandem charge-transfer chain, hence endowing the multilayered MO/(PDDA-Au-x)(n) heterostructures with significantly boosted photoelectrochemical water oxidation performance under light irradiation. The unanticipated role of PDDA as a cascade charge mediator is demonstrated to be universal. Our work would unlock the potential charge-transport capability of nonconjugated polymers as a novel charge mediator for solar-to-chemical conversion.
Reference of 1005-56-7, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 1005-56-7 is helpful to your research.