Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 586-75-4, Name is 4-Bromobenzoyl chloride, SMILES is O=C(Cl)C1=CC=C(Br)C=C1, in an article , author is Lobana, Tarlok S., once mentioned of 586-75-4, Safety of 4-Bromobenzoyl chloride.
An equimolar reaction of copper(I) chloride with the (E)-2-benzylidene-N-methylhydrazinecarbothioamide (btscH-(NHMe)-H-1) thio-ligand in acetonitrile followed by the addition of one equivalent of triphenylphosphine (Ph3P) gave crystals. The elemental analysis, and infrared and proton NMR spectra of the crystals supported the empirical composition, {CuCl(Ph3P)(btscH-(NHMe)-H-1)}, and single crystal X-ray crystallography revealed formation of the dinuclear compound, [Cu-2(mu-Cl)(2)(Ph3P)(2)(kappa S-1-btscH-(NHMe)-H-1)(2)] (1). There is intramolecular H-bonding between the hydrazinic hydrogen atom (N-2-H) and chloride ion {NH…Cl, 2.29; N…Cl, 3.144 angstrom}. The intermolecular H-bonding between the dimeric units led to the formation of a H-bonded 1 D polymer. DFT calculations on complexes of copper(I) halides with the model thiosemicarbazone, {H2C2=N-3-N(H)-C(=S)-(NHMe)-H-1}, and PH3 as a co-ligand, revealed the formation of halogen-bridged or sulfur-bridged dinuclear complexes, without or with the halogen – solvent/water hydrogen bonding. Some interesting conclusions are inferred from the experimental-theoretical correlations.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 586-75-4, you can contact me at any time and look forward to more communication. Safety of 4-Bromobenzoyl chloride.
Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics