An article Copper-catalyzed direct amination of benzylic hydrocarbons and inactive aliphatic alkanes with arylamines WOS:000532260100009 published article about BUCHWALD-HARTWIG AMINATION; CARBON-NITROGEN BONDS; C-H AMINATION; TRANSITION-METAL; AMIDATION; DISCOVERY; ARYLATION; AMMONIA in [Yao, Hua; Xie, Bo; Zhong, Xiaoyang; Jin, Shengzhou; Lin, Sen; Yan, Zhaohua] Nanchang Univ, Dept Chem, 999 Xuefu Rd, Nanchang 330031, Jiangxi, Peoples R China in 2020.0, Cited 52.0. SDS of cas: 95-49-8. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8
A new synthetic method toward direct C-N bond formation through saturated C-H amination of benzylic hydrocarbons and inactive aliphatic alkanes with primary aromatic amines under an inexpensive catalyst/oxidant (Cu/DTBP) system has been developed. Both aminopyridines and anilines could react smoothly with primary and secondary benzylic C-H substrates or cyclohexane to form the corresponding aromatic secondary amines in moderate to good yields. This protocol has the advantages of wide functional group tolerance and use of readily available raw materials.
About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yao, H; Xie, B; Zhong, XY; Jin, SZ; Lin, S; Yan, ZH or concate me.. SDS of cas: 95-49-8
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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