Brief introduction of 95-49-8

HPLC of Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yuen, OY; So, CM or concate me.

HPLC of Formula: C7H7Cl. I found the field of Chemistry very interesting. Saw the article Ligand Control of Palladium-Catalyzed Site-Selective alpha- and gamma-Arylation of alpha,beta-Unsaturated Ketones with (Hetero)aryl Halides published in 2020.0, Reprint Addresses So, CM (corresponding author), Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hung Hom, Hong Kong, Peoples R China.; So, CM (corresponding author), Hong Kong Polytech Univ, State Key Lab Chem Biol & Drug Discovery, Hung Hom, Kowloon, Hong Kong, Peoples R China.; So, CM (corresponding author), Hong Kong Polytech Univ, Shenzhen Res Inst, Shenzhen, Peoples R China.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene.

This study describes the first palladium-catalyzed, site-selective alpha- and gamma-arylation of alpha,beta-unsaturated ketones with (hetero)aryl halides. A wide range of hetero(aryl)halides coupled with alpha,beta-unsaturated ketones, and transformation into the arylated products proceeded with excellent to good yields. The site selectivity of the reaction is switchable by simply changing the phosphine ligand to access either alpha-arylated or gamma-arylated products in good to excellent yields by using a low catalyst loading, and the method demonstrates good functional-group compatibility.

HPLC of Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yuen, OY; So, CM or concate me.

Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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