Chen, MT; Hsieh, BY; Liu, YH; Wu, KH; Lussari, N; Braga, AAC in [Chen, Ming-Tsz; Hsieh, Bing-Yan; Liu, Yi-Hung] Providence Univ, Dept Appl Chem, Taichung 43301, Taiwan; [Wu, Kuo-Hui] Univ Tokyo, Grad Sch Sci, Dept Chem, Tokyo, Japan; [Lussari, Natalia; Braga, Ataualpa A. C.] Univ Sao Paulo, Inst Quim, Dept Quim Fundamental, Ave Prof Lineu Prestes 748, BR-05508000 Sao Paulo, Brazil published N,N ‘-bridged binuclear NHC palladium complexes: A combined experimental catalytic and computational study for the Suzuki reaction in 2020, Cited 96. Recommanded Product: 1-Chloro-2-methylbenzene. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.
This work examines howN-donor bridged spacer ligands affectN-heterocyclic carbene (NHC) palladium complexes catalytic activities for Suzuki coupling reaction. Different degrees of structural flexibility binuclear NHC palladium complexes were synthesized. The more flexible nitrogen-based alkyl chain ligand shows similar performance with cycloamine counterparts in the Suzuki coupling reaction. Suzuki coupling examples were used in air and ambient temperature to reach moderate to completion yields in short time. Density functional theory calculations showed that the chelate effect, associated with a single Pd complex mechanism, plays a fundamental role in the pre-catalysis stage, supporting a reasonable of the kinetic activity observed experimentally.
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Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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