Recently I am researching about N BOND-FORMATION; ONE-POT SYNTHESIS; C-H ALKOXYLATION; EFFICIENT SYNTHESIS; BENZYLIC COMPOUNDS; COUPLING REACTIONS; O BOND; INHIBITORS; DERIVATIVES; AMINATION, Saw an article supported by the Key Laboratory Open Foundation of Functional Molecular Engineering of Guangdong Province, China [2018kf09]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Zhuge, JP; Jiang, ZY; Jiang, W; Histand, G; Lin, DE. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene. Formula: C7H7Cl
An efficient oxidative functionalization of purine-like substrates with (thio)ethers or methylarenes under mild conditions is described. Using I-2 as the catalyst, and TBHP as the oxidant, this protocol provides a valuable synthetic tool for the assembly of a wide range of 9-alkyl(benzyl)purin-8-one derivatives with high atom- and step-economy and exceptional functional group tolerance.
Formula: C7H7Cl. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Zhuge, JP; Jiang, ZY; Jiang, W; Histand, G; Lin, DE or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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