Name: 1-Chloro-2-methylbenzene. I found the field of Chemistry very interesting. Saw the article Photo-Induced Chloride Atom Transfer Radical Addition and Aminocarbonylation Reactions published in 2019.0, Reprint Addresses Yuan, RS (corresponding author), Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350108, Fujian, Peoples R China.; Wang, YJ (corresponding author), Dongguan Univ Technol, Sch Environm & Civil Engn, Dongguan 523808, Peoples R China.. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene.
A photo-induced atom transfer radical addition (ATRA) of aryl chlorides onto alkenes has been developed in the synthesis of chloroalkyl benzenes, in which chlorine radicals and aryl radicals can be generated simultaneously at ambient temperature without the involvement of any initiator or catalyst. The inherently reactive and energetic chlorine radicals also benefit a photo-induced aminocarbonylation reaction of aryl chlorides with carbon monoxide and amines via a hydrogen-abstraction step. These two reactions can provide an inspiration for organic reaction with a radical-designed process. Finally, a photo-induced multi-phase reaction system is extended to flow mode to yield scaled-up products on a gram scale.
Name: 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Pan, H; Ge, HQ; He, R; Huang, WC; Wang, LL; Wei, YC; Sa, RJ; Wang, YJ; Yuan, RS or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics