An article Potent Reductants via Electron-Primed Photoredox Catalysis: Unlocking Aryl Chlorides for Radical Coupling WOS:000512222700002 published article about VISIBLE-LIGHT PHOTOREDOX; DIRECT ARYLATION; METAL-COMPLEXES; ANION-RADICALS; REDUCTION; HALIDES; BOND; FUNCTIONALIZATION; ACTIVATION; DRIVEN in [Cowper, Nicholas G. W.; Chernowsky, Colleen P.; Williams, Oliver P.; Wickens, Zachary K.] Univ Wisconsin, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA in 2020.0, Cited 79.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Name: 1-Chloro-2-methylbenzene
We describe a new catalytic strategy to transcend the energetic limitations of visible light by electrochemically priming a photocatalyst prior to excitation. This new catalytic system is able to productively engage aryl chlorides with reduction potentials hundreds of millivolts beyond the potential of Na-0 in productive radical coupling reactions. The aryl radicals produced via this strategy can be leveraged for both carbon-carbon and carbon-heteroatom bond-forming reactions. Through direct comparison, we illustrate the reactivity and selectivity advantages of this approach relative to electrolysis and photoredox catalysis.
Name: 1-Chloro-2-methylbenzene. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Cowper, NGW; Chernowsky, CP; Williams, OP; Wickens, ZK or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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