Quality Control of 1-Chloro-2-methylbenzene. Recently I am researching about ONE-POT SYNTHESIS; CARBONYL; REDUCTION; AMINATION; CLUSTERS, Saw an article supported by the CSIRCouncil of Scientific & Industrial Research (CSIR) – India [01(2996)/19/EMR-II]; MNIT Jaipur. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Srivastava, AK; Sharma, C; Joshi, RK. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
A strategy involving bimetallic catalysis with a combination of Cp*Co(CO)I-2 and Cu(OAc)(2) was used for performing Buchwald-type C-N coupling reactions of aryl chlorides with amines. The reactions proceeded at 100 degrees C to produce excellent yields of many of the desired C-N coupled products, in 4 h, under aerobic reaction conditions. The reactions were shown to run under base-free and solvent-free conditions, enabling this strategy to work efficiently for electron-withdrawing and base-sensitive functionalities. The presented methodology was found to be equally efficient for electron-donating functionalities as well as for primary (1 degrees) and secondary (2 degrees) aromatic and aliphatic amines. Moreover, the products were easily separated through the extractions of the organic aqueous layer, with this process chromatographic separations is not required.
About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Srivastava, AK; Sharma, C; Joshi, RK or concate me.. Quality Control of 1-Chloro-2-methylbenzene
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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