Product Details of 95-49-8. In 2020.0 ANGEW CHEM INT EDIT published article about O BOND FORMATION; COUPLING REACTIONS; ENANTIOSELECTIVE SYNTHESIS; CROSS-COUPLINGS; ACTIVATED ARYL; HALIDES; ETHERS; MILD; HYDROXYLATION; PHOTOREDOX in [Yang, Liu; Lu, Huan-Huan; Lai, Chu-Hui; Li, Gang; Zhang, Wei; Cao, Rui; Liu, Fengyi; Wang, Chao; Xiao, Jianliang; Xue, Dong] Shaanxi Normal Univ, Key Lab Appl Surface & Colloid Chem, Minist Educ, Xian 710062, Peoples R China; [Yang, Liu; Lu, Huan-Huan; Lai, Chu-Hui; Li, Gang; Zhang, Wei; Cao, Rui; Liu, Fengyi; Wang, Chao; Xiao, Jianliang; Xue, Dong] Shaanxi Normal Univ, Sch Chem & Chem Engn, Xian 710062, Peoples R China; [Xiao, Jianliang] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England in 2020.0, Cited 71.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8.
A highly effective C-O coupling reaction of (hetero)aryl electrophiles with primary and secondary alcohols is reported. Catalyzed by a Ni-II-aryl complex under long-wave UV (390-395 nm) irradiation in the presence of a soluble amine base without any additional photosensitizer, the reaction enables the etherification of aryl bromides and aryl chlorides as well as sulfonates with a wide range of primary and secondary aliphatic alcohols, affording synthetically important ethers. Intramolecular C-O coupling is also possible. The reaction appears to proceed via a Ni-I-Ni-III catalytic cycle.
Product Details of 95-49-8. About 1-Chloro-2-methylbenzene, If you have any questions, you can contact Yang, L; Lu, HH; Lai, CH; Li, G; Zhang, W; Cao, R; Liu, FY; Wang, C; Xiao, JL; Xue, D or concate me.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics