Recommanded Product: 50-30-6. Recently I am researching about PALLADIUM-CATALYZED ARYLATION; CROSS-COUPLING REACTIONS; AROMATIC CARBOXYLIC-ACIDS; ELECTRON-RICH OLEFINS; VINYL ETHERS; ALPHA-REGIOSELECTIVITY; VERSATILE CATALYST; MIZOROKI-HECK; ARYL; HALIDES, Saw an article supported by the INSA Rouen; Rouen University; CNRSCentre National de la Recherche Scientifique (CNRS)European Commission; EFRDEuropean Commission; European INTERREG IV A France (Channel); Labex SynOrg [ANR-11-LABX-0029]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Hachem, M; Schneider, C; Hoarau, C. The CAS is 50-30-6. Through research, I have a further understanding and discovery of 2,6-Dichlorobenzoic acid
Despite remarkable advances to promote regio- and stereoselective decarboxylative arylation of inactivated olefins with benzoic acid derivatives, methodologies involving hetero-substituted alkenes are still lacking. Herein, Pd-II-catalyzed decarboxylative Heck coupling of alpha-alkoxyacrylates with (hetero)aryl carboxylic acids for the stereocontrolled production of (Z)-beta-heteroarylated vinyl ethers is reported. This methodology offers a rational and step-economical route to the synthesis of attractive beta-arylated alpha-alkoxy alpha,beta-unsaturated carboxylates family which emerged as a relevant class of building blocks with different applications. Mechanistically, whereas electron rich benzoic acids undergo a Pd-II-catalyzed decarboxylation, electron-deficient substrates proceed through silver(I)-mediated decarboxylation, explaining thus the formation of stereoisomers (E) and (Z) of beta-arylated vinyl ethers in presence of these latter.
Recommanded Product: 50-30-6. About 2,6-Dichlorobenzoic acid, If you have any questions, you can contact Hachem, M; Schneider, C; Hoarau, C or concate me.
Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics