I found the field of Chemistry very interesting. Saw the article Alcohol Oxidations by Schiff Base Manganese(III) Complexes published in 2020. HPLC of Formula: C7H4Cl2O2, Reprint Addresses Neshat, A (corresponding author), IASBS, Dept Chem, Zanjan 4513766731, Iran.; Mastrorilli, P (corresponding author), Politecn Bari, DICATECh Dept, Via Orabona 4, I-70125 Bari, Italy.. The CAS is 50-84-0. Through research, I have a further understanding and discovery of 2,4-Dichlorobenzoic acid
Asymmetric Schiff base manganese(III) complexes involving salen ligands, N,N’-bis(salicylidene)2,3-diaminopyridine, N,N’-bis(3-methoxysalicylidene)2,3-diaminopyridine, N,N’-bis(3,5-di-tert-butylsalicylidene)2,3-diaminopyridine and N,N’-bis(3,5-di-chloro-salicylidene)2,3-diaminopyridine were prepared and their catalytic activity was investigated in the oxidation of some primary and secondary alcohols. During optimization of oxidation reactions, Mn-4, bearing electron withdrawing N,N’-Bis(3,5-di-chloro-salicylidene)2,3-diaminopyridine ligand, showed higher activity than other catalysts tested. The catalytic reactions were carried out in the presence of various oxidants such as oxygen, hydrogen peroxide or tert-butyl hydroperoxide (TBHP) and additives such as acetic acid and imidazole. The oxidant/additive combination of TBHP and imidazole was shown to be effective for the oxidation process and the degree of their impact on oxidation reaction was found highly dependent on a balanced ratio between them. Mn-4 was selected as the most effective catalyst under optimized reaction conditions and revealed efficient for the oxidation of secondary alcohols.
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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics