COA of Formula: C7H7Cl. Recently I am researching about N-HETEROCYCLIC CARBENES; MIYAURA COUPLING REACTIONS; PD-NHC PRECATALYST; SUZUKI-MIYAURA; 1.3-DIPOLARE CYCLOADDITIONEN; GOLD(I) COMPLEXES; ORGANISCHER AZIDE; PINCER LIGAND; ARYL; ESTERS, Saw an article supported by the PRODEP [UAEH-PTC-792]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: De la Fuente-Olvera, AA; Suarez-Castillo, OR; Mendoza-Espinosa, D. The CAS is 95-49-8. Through research, I have a further understanding and discovery of 1-Chloro-2-methylbenzene
A series of allyl (1-3) and cinnamyl (4-6) palladium(II) complexes supported by hydroxyl functionalized triazolylidenes have been prepared. All new compounds were fully characterized by means of H-1 and C-13 NMR spectroscopy, FT-IR and elemental analyses. The new triazolylidene palladium complexes were tested as precatalysts in the coupling of aryl chlorides with boronic acids and the coupling of esters with amines to produce biphenyls and amides, respectively. According to the overall results, complexes 4 and 5 displayed the highest catalytic activity in both coupling processes, providing good to excellent yields under mild reaction conditions and using a wide range of substrates.
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Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
Chloride – Wikipedia,
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