An article A practical copper-catalyzed approach to beta-lactams via radical carboamination of alkenyl carbonyl compounds WOS:000483700100002 published article about UNACTIVATED C(SP(3))-H BONDS; STEREOSELECTIVE-SYNTHESIS; INTRAMOLECULAR AMINATION; GAMMA-LACTAMS; SEQUENTIAL MONOARYLATION/AMIDATION; AMIDATION; ACTIVATION; CARBOXAMIDES; CYCLIZATION; ARYLATION in [Shi, Peng; Wang, Jie; Gan, Zixu; Zhao, Yingsheng] Soochow Univ, Coll Chem Chem Engn & Mat Sci, 199 Renai Rd, Suzhou, Jiangsu, Peoples R China; [Zhang, Jingyu; Zeng, Runsheng] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou, Jiangsu, Peoples R China in 2019.0, Cited 54.0. The Name is 1-Chloro-2-methylbenzene. Through research, I have a further understanding and discovery of 95-49-8. Computed Properties of C7H7Cl
Functionalized beta-lactams are highly important motifs in synthetic chemistry. We report an efficient and novel approach to the synthesis of beta-lactams via a copper(i)-catalyzed cascade process involving C(benzyl)-H radical abstraction, intermolecular alkene addition, and intramolecular amination reaction. Variously substituted alkenes were synthesized from vinylacetic acid, leading to the corresponding beta-lactams in moderate to good yields. Preliminary studies indicate that the reaction undergoes a free radical mechanism via a Cu(i)/Cu(ii)/Cu(iii) catalytic cycle.
Computed Properties of C7H7Cl. Welcome to talk about 95-49-8, If you have any questions, you can contact Shi, P; Wang, J; Gan, ZX; Zhang, JY; Zeng, RS; Zhao, YS or send Email.
Reference:
Patent; Nanjing Zhongteng Chemical Co., Ltd.; Zhong Hua; Lu Minshan; Chen Xiuzhen; Liu Qiaobao; Yin Hengbo; Wang Aili; (8 pag.)CN104876790; (2017); B;,
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