Harinath, A; Bhattacharjee, J; Panda, TK in [Harinath, Adimulam; Bhattacharjee, Jayeeta; Panda, Tarun K.] Indian Inst Technol Hyderabad, Dept Chem, Sangareddy 502285, Telangana, India published Facile reduction of carboxylic acids to primary alcohols under catalyst-free and solvent-free conditions in 2019, Cited 35. COA of Formula: C7H4Cl2O2. The Name is 2,4-Dichlorobenzoic acid. Through research, I have a further understanding and discovery of 50-84-0.
We report the development of a facile protocol for the deoxygenative hydroboration of aliphatic and aryl carboxylic acids to afford corresponding primary alcohols under solvent-free and catalyst-free conditions. The reaction proceeds under ambient temperature exhibits good tolerance towards various functional groups and generates quantitative yields. The plausible mechanism involves the formation of Lewis acid-base adducts as well as the liberation of hydrogen gas.
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Reference:
Chloride – Wikipedia,
,Chlorides – an overview | ScienceDirect Topics