Lardy, Samuel W.; Schmidt, Valerie A. published an article about the compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol( cas:35836-73-8,SMILESS:CC1(C)[C@@]2([H])CC=C(CCO)[C@]1([H])C2 ).Computed Properties of C11H18O. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:35836-73-8) through the article.
We report a radical method for the removal of benzyl and p-methoxybenzyl groups from amines and alcs. using a selective hydrogen-atom abstraction under aerobic conditions. The key usage of the strongly electrophilic thiyl radical derived from com. available pentafluorothiophenol as the H-atom abstracting agent allowed for a chemoselective abstraction process leading to C-N or C-O bond cleavage. This approach is applicable to an array of alcs. and amines, operating under aerobic conditions with no need for further addition of a stoichiometric external oxidant or hazardous reagents.
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Reference:
Chloride – Wikipedia,
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