Reference of 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about B-Iso-2-(2-diethylaminoethyl)apopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride – an improved chiral reducing agent for straight chain aliphatic ketones. Author is Weissman, Steven A.; Ramachandran, P. Veeraraghavan.
A series of chirally modified borohydrides of the type lithium B-iso-2-(alkyl)apopinocampheyl-9-borabicyclo[3.3.1]nonyl hydride were prepared to enable a strategic development of chiral reagents for the reduction of straight chain aliphatic ketones. The reagent (alkyl = 2-diethylaminoethyl) reduces 2-octanone in 82% ee, significantly higher than that obtained with NB-Enantride under identical conditions. An improved methodol. for these reductions is also described.
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