Name: Diiodo(1,5-cyclooctadiene)platinum(II). The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Bis-μ-[bis(diphenylphosphino)methane]-bis(halogenoplatinum)(Pt-Pt); dimeric complexes of platinum(I) containing a platinum-platinum bond. Author is Brown, Michael P.; Puddephatt, Richard J.; Rashidi, Mehdi; Seddon, Kenneth R..
Treatment of PtCl2L (L = Ph2PCH2PPh2) with NaBH4-MeOH followed by HCl-benzene gave the title complex (I; X = Cl). I (X = Br, I) were obtained from the chloro complex by halide exchange. Anal. of the 1H and 31P NMR and vibrational spectra of the complexes supported structure I rather than the halo-bridged structure reported by F. Glockling and R. J. I. Pollock (1974). Bands assigned to ν(Pt-Pt) are present in the Raman spectra.
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Reference:
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