Extended knowledge of 12266-72-7

From this literature《Reactions of (π-1,5-cyclooctadiene)organoplatinum(II) compounds and the synthesis of perfluoroalkylplatinum complexes》,we know some information about this compound(12266-72-7)SDS of cas: 12266-72-7, but this is not all information, there are many literatures related to this compound(12266-72-7).

SDS of cas: 12266-72-7. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Reactions of (π-1,5-cyclooctadiene)organoplatinum(II) compounds and the synthesis of perfluoroalkylplatinum complexes. Author is Clark, H. C.; Manzer, L. E..

An improved synthesis for PtR2(COD) (COD = 1,5-cyclooctadiene; R = I, Me, Et, PhCH2, Me3SiCH2, Ph) and the reactions with HCl to give PtRCl(COD) are described. The coupling constant J(Pt-H) to the olefinic carbons varies with the trans-influence of the trans-ligand. Displacement of COD from PtMe2(COD) by L (L = isocyanide, phosphine, amine, bipyridyl (bipy), Me3As) gave cis-PtMe2L2. The oxidative addition of MeI to PtR2(COD)(R = Me, Et) gave the Pt(IV) compounds [PtMe3I]4 and [PtMeEt2I]4. MeEt2PtI reacted with 4-methylpyridine (γ-Pic) to give PtEt2Me(γ-Pic)2I and with AgClO4 and pyridine to give [Pt(Et)2Mepy3](ClO4). The reaction of R2Pt(COD) (R = Me, Et) with iodine or bromine gave [PtR2X2]x. In PtMe2(CNEt)2Br2 coupling of the 14N nucleus with the Et H is observed The reaction of AcCl with PtMe2(COD) gave [PtMe2(COMe)Cl]4. γ-Picoline with the acyl compound gave 2 isomers of PtMe2(COMe)(γ-Pic)2Cl as predicted by cleavage of a cubane-type structure. The reaction of iodine with PtR2(COD)(R = CH2Ph) gave a mixture of [PtR2I2]x and PtRI(COD), whereas for R = Me3SiCH2 only PtRI(COD) was obtained. F3CI reacted with PtMe2(COD) to give Pt(CF3)2(COD) and displacement reactions of COD with ligands L, [L = CNC2H5, PhPMe2, Me3As, bipy, γ-Pic, Ph3Sb, Ph3As, Ph2PCCPPh2, Me2NCH2CH2NMe2) gave cis-Pt(CF3)2L2. Oxidative addition reactions with iodine and the stereochem. of the resultant PtIV compounds are described.

From this literature《Reactions of (π-1,5-cyclooctadiene)organoplatinum(II) compounds and the synthesis of perfluoroalkylplatinum complexes》,we know some information about this compound(12266-72-7)SDS of cas: 12266-72-7, but this is not all information, there are many literatures related to this compound(12266-72-7).

Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics