Synthetic Route of C11H18O. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about Cerium(IV) based oxidative free radical cyclization of active methylene compounds with some cyclic alkenes: A useful annulation method for terpene functionalization. Author is Svetlik, Jan; Turecek, Frantisek; Hartwich, Katarzyna; Koziel, Krzysztof; Pakulski, Pawel; Palasz, Aleksandra; Kalinowska-Tluscik, Justyna; Ciez, Dariusz.
Ceric ammonium nitrate-mediated oxidative cyclizations of CH-acids with terpenes and terpene-like substrates were investigated. Dimedone, acetylacetone, and Me nitroacetate were condensed with pinene, norbornene, nopol, camphene, and carvone and the reaction stereoselectivity was examined Condensation with endocyclic double bonds in pinene and nopol displayed stereoselectivity, resulting in the formation of pure enantiomers. Condensation with exocyclic double bonds in camphene and carvone produced enantiomer mixtures The mechanism of the intramol. annulation in a nopol derivative is discussed with the help of DFT and ab initio calculations
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