Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, Nature Catalysis called Dual-catalytic transition metal systems for functionalization of unreactive sites of molecules, Author is Lichosyt, Dawid; Zhang, Yang; Hurej, Karolina; Dydio, Pawel, which mentions a compound: 35836-73-8, SMILESS is CC1(C)[C@@]2([H])CC=C(CCO)[C@]1([H])C2, Molecular C11H18O, Product Details of 35836-73-8.
Catalytic reactions occur readily at the sites of starting materials that are both innately reactive and sterically accessible, or that are predisposed by a functional group amenable to direct a catalyst. However, selective reactions at unbiased sites of substrates remain challenging and typically require addnl. preactivation steps or the use of highly reactive reagents. Herein, report dual-catalytic transition metal systems that merge a reversible activation cycle with a functionalization cycle, which together enable the functionalization of substrates at their inherently unreactive sites. By engaging the Ru- or Fe-catalyzed equilibrium between an alc. and an aldehyde, methods for Pd-catalyzed β-arylation of aliphatic alcs. and Rh-catalyzed γ-hydroarylation of allylic alcs. were developed. The mild conditions, functional group tolerance and broad scope (81 examples) demonstrate the synthetic applicability of the dual-catalytic systems. This work highlights the potential of the multicatalytic approach to address challenging transformations to circumvent multistep procedures and the use of highly reactive reagents in organic synthesis.
When you point to this article, it is believed that you are also very interested in this compound(35836-73-8)Product Details of 35836-73-8 and due to space limitations, I can only present the most important information.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics