Category: chlorides-buliding-blocks. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about P4 Activation with Pt0 Metal Centers: Selective Formation of a Dinuclear {Pt2(μ,η2:2-P2)} Complex. Author is Demange, Matthieu; Le Goff, Xavier-Frederic; Le Floch, Pascal; Mezailles, Nicolas.
The strong activation of white phosphorus by an unsaturated, electron-rich, Pt center is presented here. It resulted in the splitting of initial P4 mol. into polymeric red phosphorus and a formally P24- coordinated fragment. The mechanism of this transformation was calculated by DFT, which corroborated the exptl. facts. Most importantly, DFT calculations point out the high electron d. at the bridging P atoms in four high-energy orbitals. Preliminary reactivity results showed the accessibility of the P lone pairs, opening the way for further functionalization of the activated fragment.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics