So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Petz, Wolfgang; Oxler, Florian; Neumueller, Bernhard researched the compound: Diiodo(1,5-cyclooctadiene)platinum(II)( cas:12266-72-7 ).Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II).They published the article 《The reaction of the betaine-like compound O2C2(PPh3)2 with [(cod)PtI2]; crystal structure of the salt (HC{PPh3}2)[(η3-C8H11)PtI2]》 about this compound( cas:12266-72-7 ) in Zeitschrift fuer Anorganische und Allgemeine Chemie. Keywords: platinum cyclooctadiene halide salt like carbodiphosphorane complex preparation; crystal structure platinum cyclooctadiene iodide carbodiphosphorane complex isomer preparation; mol structure platinum cyclooctadiene iodide carbodiphosphorane complex isomer. We’ll tell you more about this compound (cas:12266-72-7).
The reaction of the betaine-like compound O2C2(PPh3)2 (1) with [(cod)PtX2] in THF gives the salt-like compounds (HC{PPh3}2)[(η3-C8H11)PtX2] [X = iodo (3), Cl] in about quant. yields. The new η3-bonded C8H11 ligand is the result of a proton transfer from the coordinated cod ligand to 1 with subsequent release of CO2. The x-ray anal. of 3 shows 2 isomers in a 60:40 ratio, which differ in the bonding of the C8H11 ligand [triclinic, space group P1̅, a 1091.7(1), b 1141.5(1), c 1649.4(2) pm; α 80.34(1), β 83.62(1), γ 89.03(1)°, V 2013.7(4)·106 pm3, Z = 2].
In some applications, this compound(12266-72-7)Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II) is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics