The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis and structural study of (8-phenylsulfanylnaphth-1-yl)diphenylphosphine metal complexes, the main research direction is phenylsulfanyl naphthyl diphenylphosphine platinum ruthenium preparation crystal mol structure; thio phosphino naphthalene platinum ruthenium preparation crystal mol structure.Reference of Diiodo(1,5-cyclooctadiene)platinum(II).
A series of three platinum(II) halide complexes 2-4 [Pt(X)2{Nap(PPh2)(SPh)}] (Nap = naphthalene-1,8-diyl; X = Cl, Br, I) and a ruthenium(II) p-cymene complex 5 [Ru(η6-MeC6H4iPr)(Cl){Nap(PPh2)(SPh)}]+Cl- of the sterically crowded peri-substituted naphthalene phosphine 1 have been prepared The compounds were fully characterised by multinuclear NMR, IR and MS and x-ray data for 1-5 are compared. Mol. structures are analyzed by naphthalene ring torsions, peri-atom displacement, splay angle magnitude, P···S interactions, aromatic ring orientations and geometry around the metal center. Platinum adopts a strictly square planar geometry which increases the distortion of the naphthalene skeleton in 2-4. Conversely, the classical-piano stool conformation of 5 results in a pseudo-octahedral conformation around the ruthenium atom which influences the naphthalene geometry to a much lesser extent with distortion of a similar magnitude to the free ligand 1.
From this literature《Synthesis and structural study of (8-phenylsulfanylnaphth-1-yl)diphenylphosphine metal complexes》,we know some information about this compound(12266-72-7)Reference of Diiodo(1,5-cyclooctadiene)platinum(II), but this is not all information, there are many literatures related to this compound(12266-72-7).
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