Hu, Huayou; Chen, Si-Jie; Mandal, Mukunda; Pratik, Saied Md; Buss, Joshua A.; Krska, Shane W.; Cramer, Christopher J.; Stahl, Shannon S. published the article 《Copper-catalyzed benzylic C-H coupling with alcohols via radical relay enabled by redox buffering》. Keywords: alc aryl alkane copper catalyst oxidative cross coupling; aryl ether preparation.They researched the compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol( cas:35836-73-8 ).Related Products of 35836-73-8. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:35836-73-8) here.
Copper-catalyzed oxidative cross-coupling of benzylic C-H bonds with alcs. to afford benzyl ethers, enabled by a redox buffering strategy that maintains the activity of the copper catalyst throughout the reaction was reported. The reactions employ the C-H substrate as the limiting reagent and exhibit broad scope with respect to both coupling partners. This approach to direct site-selective functionalization of C(sp3)-H bonds provides the basis for efficient three-dimensional diversification of organic mols. and should find widespread utility in organic synthesis, particularly for medicinal chem. applications.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics