Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 12266-72-7, is researched, SMILESS is I[Pt]I.C1=CCC/C=CCC/1, Molecular C8H12I2PtJournal, Article, Dalton Transactions called Reaction of a heterotopic P,SAs ligand with group 10 metal(II) complexes: As-S bond cleavage and the formation of two unusual trinuclear structural isomers for Pd and Pt, Author is Sarosi, Imola; Hildebrand, Alexandra; Loennecke, Peter; Silaghi-Dumitrescu, Luminita; Hey-Hawkins, Evamarie, the main research direction is preparation trinuclear palladium platinum diphenylphosphinobenzenethiolate halo complex; mononuclear nickel palladium platinum diphenylphosphinobenzenethiolate halo complex preparation; isomerization mononuclear trinuclear nickel palladium platinum diphenylphosphinobenzenethiolate halo complex; group 10 metal phosphinophenylthioarsine complex preparation diphenylphosphinobenzenethiolate precursor; crystal structure trinuclear palladium platinum diphenylphosphinobenzenethiolate halo complex.Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II).
The synthesis of the heterotopic P,SAs ligand, 1,2-(Ph2AsS)(Ph2P)C6H4 (1) and its reaction with [PdCl2(cod)], [PtI2(cod)] (cod = 1,5-cyclooctadiene) and NiCl2·6H2O is reported. Cleavage of the As-S bond of 1 and coordination of the resulting phosphanylthiolato ligand was observed with formation of [M(P,S)2] (M = Ni, Pd, Pt; P,S = SC6H4-2-PPh2). In the case of Pd and Pt, not only the mononuclear complexes [M(P,S)2] formed, but also the trimers [MX(P,S)]3 ([MX{(μ-S-SC6H4-2-PPh2)-κ2S,P}]3 [M = Pd, X = Cl (2) and M = Pt, X = I (4)]). Formation of 2 and 4 was preceded by the trinuclear isomeric intermediates [(cis-M{(μ-S-SC6H4-2-PPh2)-κ2S,P}2)-MX2-MX{(μ-S-SC6H4-2-PPh2)-κ2S,P}] [M = Pd, X = Cl (3) and M = Pt, X = I (5)]. The crystal structures of 1-5 and a possible reaction mechanism that leads to 2 and 4 are presented.
Here is just a brief introduction to this compound(12266-72-7)Recommanded Product: Diiodo(1,5-cyclooctadiene)platinum(II), more information about the compound(Diiodo(1,5-cyclooctadiene)platinum(II)) is in the article, you can click the link below.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics