Recommanded Product: 12266-72-7. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Trimetallic complexes of the tripod ligand 1,1,1-tris(diphenylphosphinomethyl)ethane. Part I. Homotrimetallic cis,cis,cis and cis,trans,cis complexes of the type [(PtX2-η-tripod)2PtX2] (X = Cl, I and CH3). Author is Khan, A. Rauf; Socol, Steven M.; Meek, Devon W..
Cis,cis,cis- and cis,trans,cis-[(PtX2-η-tripod)2PtX2] (X = Cl, I and Me; tripod = 1,1,1-tris(diphenylphosphinomethyl)ethane) were isolated and were shown by both 31P and 195Pt NMR spectroscopy to possess phosphino-bridged trimetallic structures. The assignment of these structures is established from 1J(Pt-P) couplings and the coordination chem. shift, ΔP, of the dangling phosphino group of the monometallic complexes upon coordination. In both cis,cis,cis and cis,trans,cis geometries, the 31P NMR chem. shift of the chelating P atoms and the 195Pt NMR chem. shift for the [PtX2(tripod)] complexes remain unperturbed upon coordination of the previously noncoordinated P. For the monomeric complexes of tripod, trends in the 31P and 195Pt NMR chem. shifts as a function of X parallel those which were previously reported for analogous complexes which contain monodentate ligands.
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