So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Neve, Francesco; Ghedini, Mauro researched the compound: Diiodo(1,5-cyclooctadiene)platinum(II)( cas:12266-72-7 ).COA of Formula: C8H12I2Pt.They published the article 《Heterodinuclear nitrosyl complexes. Part 3. New organometallic nitrosyls of iridium(III) and platinum》 about this compound( cas:12266-72-7 ) in Inorganica Chimica Acta. Keywords: heterodinuclear organometallic nitrosyl complex; iridium platinum bridging nitrosyl. We’ll tell you more about this compound (cas:12266-72-7).
Treatment of the NO linearly bonded species [Ir(NO)(dppn)(PPh3)2][PF6]2 [dppn = 3,6-bis(2′-pyridyl)pyridazine] with X- (X = Cl or I) yields the bent, terminal nitrosyl complexes [Ir(NO)(X)(dppn)(PPh3)][PF6]. These complexes react with [PtCl(Me)(DMSO)2] or [PtI(R)(COD)] (R = Me or Ph, COD = cycloocta-1,5-diene) to give heterodinuclear [(PPh3)(X)2Ir(dppn)(NO)Pt(R)][PF6] (I; X = Cl, R = Me; X = I, R = Me or Ph). The spectroscopic data suggest the presence of a bridging NO group in the mixed compounds
As far as I know, this compound(12266-72-7)COA of Formula: C8H12I2Pt can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics