Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis, characterization, and reactivity of platinum(II) complexes of a mesocyclic ligand, 5-phenyl-1-thia-5-phosphacyclooctane.Recommanded Product: 12266-72-7.
5-Phenyl-1-thia-5-phosphacyclooctane (X = Cl, I), Pt(Me)LCl and cis-[PtL2](BPh4)2 were prepared and characterized. The solution-phase structures of the complexes were supported by 31P NMR studies and crystal structure determinations The crystal structure of [Pt(η4-L1)]Cl2 (L1 = 5,13-diphenyl-1,9-dithia-5,13-diphosphacyclohexadecane) is also reported. The reactions of Pt(Me)LCl with a variety of substrates were examined by 31P NMR spectroscopy: [Pt-a-Me-bc(η2-L)-d-PPh3]Cl and cis-Pt2(η1-L)2Me2Cl2(μ-DPP) were formed when Pt(Me)LCl was treated with PPh3 and 1,3-bis(diphenylphosphino)propane (DPP), resp. PtLCl2.MeCN is monoclinic, space group P21/c, Z = 4. [Pt(η4-L1)]Cl2 is triclinic, space group P1̅, Z = 1. PtI2L is monoclinic, space group C2/c, Z = 8. PtLMeCl.CH2Cl2 is triclinic, space group P1̅, Z = 4. cis-[PtL2](BPh4)2 is monoclinic, space group P21/n, Z = 4.
In addition to the literature in the link below, there is a lot of literature about this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Recommanded Product: 12266-72-7, illustrating the importance and wide applicability of this compound(12266-72-7).
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics