Quality Control of Diiodo(1,5-cyclooctadiene)platinum(II). Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Platinum(II) complexes of unsymmetrical, potentially bidentate ligands. Author is Anderson, Gordon K.; Kumar, Ravi.
The reactions of Ph2P(CH2)nX (n = 2, X = OMe, NMe2, SMe; n = 3, X = NMe2) with [PtX2(cod)] (X = Cl, I; cod = cycloocta-1,5-diene) are described. The tendency of the ligand to bond to the metal in a bidentate fashion is dependent on the nature of the weak donor, and on the size of the chelate ring formed. Halide abstraction by Ag+ promotes coordination of the ether function to yield [PtCl(PH2PCH2CH2OMe)2]+ and [Pt(Ph2PCH2CH2OMe)2]2+. Reactions of the former with a number of weak donor ligands were studied by 31P{1H} NMR spectroscopy. Complex mixtures were obtained with Ph2PCH2CH2SMe, and the involvement of ion-paired species is suggested in this case.
As far as I know, this compound(12266-72-7)Quality Control of Diiodo(1,5-cyclooctadiene)platinum(II) can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics