The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about The carbodiphosphorane-CS2 adduct as a complex ligand: Crystallographic characterization of [I2Pt{S2CC(PPh3)2}]·CH2Cl2, [Pt{S2CC(PPh3)2}2][SiF5]2·2CH2Cl2 and [(Me)2PtFI{S2CC(PPh3)2}]·2CH2Cl2, the main research direction is platinum phosphonio ethenedithiolate complex preparation structure; crystal structure platinum phosphonio ethenedithiolate complex.HPLC of Formula: 12266-72-7.
The betaine-like compound S2CC(PPh3)2 (1), which was obtained from CS2 and the double ylide C(PPh3)2, reacts with [X2Pt(COD)] (X = Cl, I) in THF to afford [X2Pt{S2CC(PPh3)2}] (2, X = Cl; 3, X = I) in quant. yields. Both compounds are insoluble in all usual solvents, and 3 could be characterized by an x-ray anal. For comparison, the structures of [Pt(Me)2FI{S2CC(PPh3)2}]·2CH2Cl2 (4·2CH2Cl2) with PtIV and [Pt{S2CC(PPh3)2}2][SiF5]2·2CH2Cl2 (5·2CH2Cl2) with PtII are also presented. The compounds are further characterized by 31P NMR and IR spectroscopy.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics