The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol, is researched, Molecular C11H18O, CAS is 35836-73-8, about Cyclopentadiene annulation via the Skatteboel rearrangement: (1R)-9,9-dimethyltricyclo-[6.1.1.02,6]deca-2,5-diene, the main research direction is nopadiene cycloaddition dibromocarbene; norpinene dimethylvinyl cycloaddition bromocarbene; bicycloheptene dibromocyclopropyl Skatteboel rearrangement; cyclopropylbicycloheptene Skatteboel rearrangement; tricyclodecadiene dimethyl.Recommanded Product: 2-((1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethanol.
The cycloaddition of dibromocarbene with (1R)-nopadiene and sequential Skatteboel rearrangement gave the title compound (I) via the diastereomeric 2-(2,2-dibromocyclopropyl)-7,7-dimethylbicyclo[3.1.1]hept-2-ene as intermediate.
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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics