New downstream synthetic route of 12266-72-7

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Jacobsen, Grant B.; Shaw, Bernard L.; Thornton-Pett, Mark published the article 《Synthesis and x-ray crystal structure of the heterobimetallic complex tricarbonyl[μ-bis(diphenylphosphino)methane]-μ-iodoiodoironplatinum》. Keywords: crystal structure iron platinum diphosphinomethane; structure iron platinum carbonyl diphosphinomethane; iron platinum carbonyl phosphinomethane iodo.They researched the compound: Diiodo(1,5-cyclooctadiene)platinum(II)( cas:12266-72-7 ).Related Products of 12266-72-7. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:12266-72-7) here.

Treatment of Fe(CO)4(dppm) (dppm = (Ph2P)2CH2) with PtI2(COD) (COD) = cyclooctadiene) in CH2Cl2 gave [(OC)3Fe(μ-dppm)(μ-I)PtI] (I) which was also obtained from [(OC)3Fe(μ-dppm)(μ-CO)PtBr2] with MeI in CH2Cl2. I was characterized by x-ray crystal structure anal. and IR spectra. The metal-metal bonding in I is viewed as a donor-acceptor type, Fe → Pt. The bridging iodo is almost sym. located between the Pt and Fe atoms. The valences of Fe and Pt in I are 0 and 2+.

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Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics