In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Cyclopropanation of Terminal Alkenes through Sequential Atom-Transfer Radical Addition/1,3-Elimination, published in 2019, which mentions a compound: 35836-73-8, mainly applied to cyclopropane derivative preparation; terminal alkene cyclopropanation radical addition; alkenes; cyclopropanation; iodine; organoboron compounds; radical reactions, Category: chlorides-buliding-blocks.
An operationally simple method to affect an atom-transfer radical addition of com. available ICH2Bpin to terminal alkenes has been developed. The intermediate iodide can be transformed in a one-pot process into the corresponding cyclopropane upon treatment with a fluoride source. This method is highly selective for the cyclopropanation of unactivated terminal alkenes over non-terminal alkenes and electron-deficient alkenes. Due to the mildness of the procedure, a wide range of functional groups such as esters, amides, alcs., ketones, and vinylic cyclopropanes are well tolerated.
The article 《Cyclopropanation of Terminal Alkenes through Sequential Atom-Transfer Radical Addition/1,3-Elimination》 also mentions many details about this compound(35836-73-8)Category: chlorides-buliding-blocks, you can pay attention to it, because details determine success or failure
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics