Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis, X-ray, spectroscopic and a preliminary Suzuki coupling screening studies of a complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I).Related Products of 12266-72-7.
A complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I) compounds were synthesized using different routes, and characterized fully. The synthesis of dppfPdI2 was achieved by reacting Pd(COD)Cl2 with dppf in the presence of NaI. X-ray structures of dppfPdBr2 and dppfPdI2 also are reported for the 1st time. A preliminary Suzuki coupling screening study reveals that dppfPdX2 compounds are superior to the conventional Ph3P-based catalysts and bidentate phosphine-based ligands. Reactions carried out under in situ conditions also gave a similar trend, but their resp. activities were much lower than that of the fully formed catalysts.
The article 《Synthesis, X-ray, spectroscopic and a preliminary Suzuki coupling screening studies of a complete series of dppfMX2 (M = Pt, Pd; X = Cl, Br, I)》 also mentions many details about this compound(12266-72-7)Related Products of 12266-72-7, you can pay attention to it, because details determine success or failure
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics