The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Thermolysis mechanism of symmetrical and unsymmetrical dialkylplatinum(II) complexes with tertiary phosphine ligands. Controlling factors for β-elimination, the main research direction is thermolysis dialkylplatinum phosphine complex; platinum dialkyl elimination reaction.Related Products of 12266-72-7.
A series of sym. and unsym. cis-dialkylplatinum(II) complexes with tertiary phosphine ligands, cis-RR1PtL2 [I; R, R1 = Me, Et, Pr, Me2CH, Me2CHCH2, n-pentyl, PhCH2CH2, p-MeOC6H6CH2CH2; L2 = (PPh3)2, (PPhMe2)2, Ph2PCH2CH2PPh2] were prepared by reaction of RPtL2Cl with alkylating reagents such as R1Li and R1MgX. Thermolysis of I gives only the disproportionation products of the 2 alkyl groups via β-elimination. A kinetic study of the thermolysis reveals the existence of a nondissociative path in addition to a dissociative one. In the presence of excess PPh3 thermolysis proceeds mainly via a nondissociative path in which olefin liberation after facile reversible β-elimination is probably rate-determining In thermolysis of the unsym. I in the absence of excess PPh3, the relative rate of β-elimination of R to that of R1 is proportional to the ratio of the number of β-H atoms in R to that in R1.
The article 《Thermolysis mechanism of symmetrical and unsymmetrical dialkylplatinum(II) complexes with tertiary phosphine ligands. Controlling factors for β-elimination》 also mentions many details about this compound(12266-72-7)Related Products of 12266-72-7, you can pay attention to it, because details determine success or failure
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics