Electric Literature of C8H12I2Pt. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Diiodo(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12I2Pt, CAS is 12266-72-7, about Synthesis and structural characterization of a tetranuclear platinum(II) metallamacrocycle containing 1,3-diisocyanoarene ligands.
A new tetranuclear platinum(II) metallamacrocycle, including four 1,3-diisocyanoarene ligands, was synthesized and characterized. The reaction of PtI2(cod) with an equimolar amount of the 1,3-diisocyanoarene ligand in dichloromethane under diluted conditions gave the metallamacrocycle [(PtI2)4(1,3-diisocyanoarene)4]. X-ray crystallog. anal. showed that the complex adopted a square ring structure with trans arrangement of coordinated isocyanides around the Pt atoms. GPC, ESI-MS, IR, and NMR anal. of the metallamacrocycle showed that the tetranuclear macrocyclic scaffold was maintained in solution The shape and dimensions of the interior cavity was estimated by force field simulations.
Different reactions of this compound(Diiodo(1,5-cyclooctadiene)platinum(II))Electric Literature of C8H12I2Pt require different conditions, so the reaction conditions are very important.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics