Liu, Minghui;Wei, Changgeng;Zhuzhang, Hangyu;Zhou, Jingmin;Pan, Zhiming;Lin, Wei;Yu, Zhiyang;Zhang, Guigang;Wang, Xinchen published 《Fully Condensed Poly(Triazine Imide) Crystals: Extended π-Conjugation and Structural Defects for Overall Water Splitting》. The research results were published in《Angewandte Chemie, International Edition》 in 2022.Reference of Rubidiumchloride The article conveys some information:
Conventional polymerization for the synthesis of carbon nitride usually generates amorphous heptazine-based melon with an abundance of undesired structural defects, which function as charge carrier recombination centers to decrease the photocatalytic efficiency. Herein, a fully condensed poly(triazine imide) crystal with extended π-conjugation and deficient structure defects was obtained by conducting the polycondensation in a mild molten salt of LiCl/NaCl. The m.p. of the binary LiCl/NaCl system is around 550°, which substantially restrain the depolymerization of triazine units and extend the π-conjugation. The optimized polymeric carbon nitride crystal exhibits a high apparent quantum efficiency of 12% (λ=365 nm) for hydrogen production by one-step excitation overall water splitting, owing to the efficient exciton dissociation and the subsequent fast transfer of charge carriers. To complete the study, the researchers used Rubidiumchloride (cas: 7791-11-9) .
Rubidium chloride(cas: 7791-11-9) can increases dopamine and norepinephrine levels, and useful for anergic and apathetic depressives.Reference of Rubidiumchloride Pharmaceutical compositions have been used as antidepressants in Europe. It is employed in biochemistry to induce cells to take up DNA.
Reference:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics