Chloride substituents modify the physical properties of organic compounds in several ways. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Chakrabarty, Aditya;Mukherjee, Santanu research published 《 Iridium-Catalyzed Enantioselective and Chemodivergent Allenylic Alkylation of Vinyl Azides for the Synthesis of α-Allenylic Amides and Ketones》, the research content is summarized as follows. The first enantioselective synthesis of α-allenylic amides and ketones through allenylic alkylation of vinyl azides was reported. In these chemodivergent reactions, cooperatively catalyzed by a IrI/(phosphoramidite, olefin) complex and Sc(OTf)3, vinyl azides acted as the surrogate for both amide enolates and ketone enolates. The desiccant (mol. sieves) played a crucial role in controlling the chemodivergency of this enantioconvergent and regioselective reaction, under otherwise identical reaction conditions, the presence of the desiccant led to α-allenylic amides, while its absence resulted in α-allenylic ketones. Utilizing racemic allenylic alcs. as the alkylating agent, the overall process represents a dynamic kinetic asym. transformation (DyKAT), where both the products were formed with the same absolute configuration.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics