Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 104-86-9, formula is C7H8ClN, Name is (4-Chlorophenyl)methanamine. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Related Products of 104-86-9.
Chen, Huiling;Liu, Cheng;Guo, Wei;Wang, Zhiwen;Shi, Yingzhang;Yu, Yan;Wu, Ling research published 《 Functionalized UiO-66(Ce) for photocatalytic organic transformation: the role of active sites modulated by ligand functionalization》, the research content is summarized as follows. In this work, a series of functionalized UiO-66(Ce)-X (X = H, CH3, Br, NO2) was successfully synthesized for the photocatalytic oxidation of benzylamines under visible light. The UiO-66(Ce)-CH3 exhibited the highest conversion among the samples. The quantity and the acid strength of coordinatively unsaturated Ce sites as Lewis acid sites were modulated by ligand functionalization, both following the order of UiO-66(Ce)-CH3 > UiO-66(Ce)-H > UiO-66(Ce)-Br > UiO-66(Ce)-NO2, which was closely related to photocatalytic performance. Based on in situ FTIR results, coordinatively unsaturated Ce sites could facilitate the activation of benzylamine mols. via the surface -Ce···N-coordination species, and the activated degree of the N-H bonds was evaluated and compared via the force constant In the photocatalytic process, photogenerated holes achieved the deprotonation of activated benzylamine mols. to form benzylamine cations, and photogenerated electrons captured by oxygen vacancies simultaneously reduced activated O2 to form O2-, effectively achieving this selective photooxidation Finally, a synergetic photocatalytic mechanism associated with the coordination activation was proposed to explain this reaction process.
104-86-9, 4-Chlorobenzylamine is a useful research compound. Its molecular formula is C7H8ClN and its molecular weight is 141.6 g/mol. The purity is usually 95%.
4-Chlorobenzylamine is a reactant in the environmentally friendly synthesis of pyrroles.
4-Chlorobenzylamine is a chemical that is used as an intermediate in the synthesis of other compounds. It has low bioavailability, which may be due to its reactive site. The chemical can be characterized using nmr spectra and potent inhibitory activity. 4-Chlorobenzylamine has been found to react with nitrogen atoms, and this reaction is highly acidic. FT-IR spectroscopy can also be used to characterize this compound. Intermolecular hydrogen bonding and hydroxyl group are two of the major interactions of 4-chlorobenzylamine with other molecules. This chemical reacts with serine protease, glyoxal, and other substances in a manner that depends on the molecule’s structure., Related Products of 104-86-9
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics