The class of organic compounds having covalently a bonded chlorine atom is called organic chlorides. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of named reactions and applications. Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Daubit, Isabelle Marie;Wortmann, Svenja;Siegmund, Daniel;Hahn, Stephan;Nuernberger, Patrick;Metzler-Nolte, Nils research published 《 Unveiling Luminescent Ir(I) and Rh(I) N-Heterocyclic Carbene Complexes: Structure, Photophysical Specifics, and Cellular Localization in the Endoplasmic Reticulum》, the research content is summarized as follows. Complexes of Rh(I) and Ir(I) of the [M(COD)(NHC)X] type (M = Rh or Ir, COD = 1,5-cyclooctadiene, NHC = N-heterocyclic carbene, and X = halide) have recently shown promising cytotoxic activities against several cancer cell lines. Initial mechanism of action studies provided some knowledge about their interaction with DNA and proteins. However, information about their cellular localization remains scarce owing to luminescence quenching within this complex type. Herein, the synthesis of two rare examples of luminescent Rh(I) and Ir(I) [M(COD)(NHC)I] complexes with 1,8-naphthalimide-based emitting ligands is reported. All new complexes are comprehensively characterized, including with single-crystal x-ray structures. Steric crowding in one derivative leads to two distinct rotamers in solution, which apparently can be distinguished both by pronounced NMR shifts and by their resp. spectral and temporal emission signatures. When the photophys. properties of these new complexes are exploited for cellular imaging in HT-29 and PT-45 cancer cell lines, the complexes accumulate predominantly in the endoplasmic reticulum, which is an entirely new finding and provides the 1st insight into the cellular localization of such Ir(I)(NHC) complexes.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics