Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Durran, Sean E.;Elsegood, Mark R. J.;Noble, Thomas A.;Smith, Martin B.;Gelbrich, Thomas;Hursthouse, Michael B.;Light, Mark E. research published 《 Synthesis and Characterisation of Transition Metal Complexes of a Novel 1,5-benzodiazepine-Functionalised Tertiary Phosphine》, the research content is summarized as follows. The 1-step synthesis (44% isolated yield) of the 1,5-benzodiazapine functionalized phosphine 1, C31H31N2OP, is reported. Bridge cleavage of {MCl(μ-Cl)(η5-Cp*)}2 (M = Ir, Rh) with 2 equiv of 1 in CH2Cl2 gave mononuclear [MCl2(η5-Cp*)(P-1)] (M = Ir, 2a; M = Rh, 2b) in which 1 functions as a P-monodentate ligand. Rapid C(sp3)-H bond activation, at room temperature, is observed for 2a leading to the unusual cyclometalated complex [Ir(η5-Cp*)(P,N,C-1)]Cl2 3 (or 3‘) bearing an anionic P/Namine/C-terdentate ligand. Reaction of [PtMeCl(η4-cod)] with one equivalent of 1 led to [PtMeCl(P,N-1)] 4, suggesting that 3 may form via an intermediate Ir(III) cationic species in which the ligand is P,N-bound. The IrI complex [IrCl(η4-cod)(P-1)] 5 does not, under similar conditions, show any evidence for C-H activation. Single crystal x-ray studies on 1, 2a, 2b, 3, 3‘, 4, and 5 reveal intramol. N ··· H-O H-bonding in all cases.
Name: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics