Chukicheva, I. Yu.;Krylova, M. V.;Buravlev, E. V.;Suponitskii, K. Yu.;Kutchin, A. V. published 《Alkylation of 2,4-dimethylphenol with (+)-α- and (-)-β-pinenes in the presence of aluminum xylenolate》. The research results were published in《Russian Journal of Organic Chemistry》 in 2014.Synthetic Route of C10H13ClO3 The article conveys some information:
Alkylation of 2,4-dimethylphenol with (+)-α- and (-)-β-pinenes in the presence of aluminum 2,4-dimethylphenoxide generated in situ gave mixtures of products, from which optically active compounds were isolated. The structure of 2-bornyl-4,6-dimethylphenol was determined by x-ray anal.; its (+)- and (-)-enantiomers were assigned (1R,2R,4S) and (1S,2S,4R) configurations, resp. And (1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride(Chunks or pellets) (cas: 39637-74-6) was used in the research process.
(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride(Chunks or pellets) (cas: 39637-74-6 Synthetic Route of C10H13ClO3) is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.
Reference:
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