Organic chloride is an organic compound containing at least one covalently bonded atom of chlorine. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Their wide structural variety and divergent chemical properties lead to a broad range of names and applications. Synthetic Route of 12112-67-3.
Gauthier, Etienne S.;Cordier, Marie;Dorcet, Vincent;Vanthuyne, Nicolas;Favereau, Ludovic;Williams, J. A. Gareth;Crassous, Jeanne research published 《 Helically Chiral NHC-Gold(I) Complexes: Synthesis, Chiroptical Properties and Electronic Features of the [5]Helicene-Imidazolylidene Ligand》, the research content is summarized as follows. We describe the preparation of helically chiral gold(I) complexes bearing a [5]helicenic-N-heterocyclic carbene ligand. They were successfully obtained as enantiopure compounds by semi-preparative chiral HPLC and their structural, chiroptical, and photophys. properties were subsequently investigated. Notably, strong electronic CD, dual emission from singlet and triplet states, with the timescale of the latter up to the millisecond range at room temperature, and moderate circularly phosphorescence were observed The σ-donating and π-accepting properties of the constituent helical ortho-fused π-conjugated carbene were investigated by classical quant. anal. of the IR stretching frequencies and NMR characteristics of the corresponding Ir(CO)2Cl complex and selenourea.
12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
, Synthetic Route of 12112-67-3
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics