Chloride substituents modify the physical properties of organic compounds in several ways. 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. They are typically denser than water due to the presence of chlorine, which has a high atomic weight. Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer.
Gillaizeau, Isabelle;Dondasse, Ismael;Nicolas, Cyril;Mimoun, Liliane;Sukach, Volodymyr;Meudal, Herve research published 《 Iridium-Catalyzed β-C(sp2)-H Borylation of Enamides – Access to 3,3-Dihalogeno-2-methoxypiperidines》, the research content is summarized as follows. An efficient catalytic preparation of synthetically useful new α,β-unsaturated β-borylated enamides was achieved under relatively mild conditions via a regioselective iridium-catalyzed C(sp2)-H dehydrogenative borylation of enamides with B2pin2. The method features broad substrate scope, good functional group tolerance and efficient scale-up. These C-3 borylated enamides can be advantageously exploited in cross-coupling reactions and converted into valuable 3,3-dihalogeno-2-methoxypiperidines in very short reaction times.
Recommanded Product: Chloro(1,5-cyclooctadiene)iridium(I) dimer, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics