Organic chlorides are organic molecules with a C-Cl bond, for example chloroform (CH3-Cl) or vinyl chloride(C2H3Cl). 12112-67-3, formula is C16H24Cl2Ir2, Name is Chloro(1,5-cyclooctadiene)iridium(I) dimer. Organic chlorides can be used in production of: PVC, Organic chlorides can cause corrosion in pipelines, valves and condensers, and cause catalyst poisoning. Application In Synthesis of 12112-67-3.
Grimm, Alexandra B.;Wang, Kai;Rheingold, Arnold L.;Moore, Curtis E.;Szieberth, Denes;Nyulaszi, Laszlo;Protasiewicz, John D. research published 《 2-Aryl-1,3-Benzoxaphospholes as Unwilling Participants for Catalytic Suzuki-Miyaura CC Coupling Reactions》, the research content is summarized as follows. Under conditions typically effective to achieve a catalytic aryl-aryl bond during Pd Suzuki-Miyaura (SM) coupling reactions of ArB(OH)2 and ArBr, reactions of p-tolylboronic acid and 2-(BrC6H4)-1,3-benzoxaphosphole (BrC6H4-BOP, 1) failed to provide the anticipated product of CC bond coupling, 2-(p-CH3C6H4-C6H4)-1,3-benzoxaphosphole. An anal. of reaction mixtures by 1H and 31P{1H} NMR spectroscopic methods showed numerous broad resonances, suggesting the formation of labile metal complexes with 1. This possibility was confirmed by determinations of the solid-state structures of [(tBu3P)(Ph-BOP)M]2 (M = Pt, 5; M = Pd, 6) from the reaction of Ph-BOP and [M(tBu3P)2] (M = Pt, Pd). The structures of 5 and 6 are isomorphous and reveal unusual bridging μ2-P-BOP bonding modes. Computational studies have explored the structures and relative energies and indicate that dimeric complexes of this form can dissociate easily. Surprisingly, even when P:C double bonds of Ar-BOPs are sheltered by coordination to W pentacarbonyl, the Ar-BOP units resist yielding products of CC coupling under similar SM conditions but instead yield unusual products whereby CsOH adds across the P:C bonds in [(CO)5W{2-Ar-BOP}]. Computational studies are consistent with ready addition of hydroxide to the W-protected P:C bond.
Application In Synthesis of 12112-67-3, Bis(1,5-cyclooctadiene)diiridium(I) is a useful research compound. Its molecular formula is C16H24Cl2Ir2-2 and its molecular weight is 671.7 g/mol. The purity is usually 95%.
Bis(1,5-cyclooctadiene)diiridium(I) Dichloride is a catalyst used in the iridium-catalyzed asymmetry hydrogenation of unfunctionalized exocyclic double carbon bonds. Also, it is used to test new NeoPHOX ligands derived from serine or threonine.
Bis(1,5-cyclooctadiene)diiridium(I) dichloride is an acid that can be prepared using a preparative method. It is an organometallic compound that can be used in the cross-coupling of activated terminal alkynes with aryl halides. Bis(1,5-cyclooctadiene)diiridium(I) dichloride has been synthesized by reacting furfural with chloride and acetonitrile. The ligand used was 2,2′-bipyridine. The reaction time to produce bis(1,5-cyclooctadiene)diiridium(I) dichloride is approximately three hours.
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Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics