Banovetz, Haley K.; Vickerman, Kevin L.; David, Colton M.; Alkan, Melisa; Stanley, Levi M. published the artcile< Palladium-Catalyzed Intermolecular Alkene Carboacylation via Ester C-O Bond Activation>, SDS of cas: 17082-09-6, the main research area is functionalized ketone diastereoselective preparation; ester preparation bicyclic alkene tetraarylborate carboacylation palladium catalyst.
Palladium-catalyzed intermol. carboacylation of alkenes with ester electrophiles and tetraarylborate nucleophiles was reported. Bicyclic alkenes reacted with a variety of pentafluorophenyl benzoate and alkanoate esters and sodium tetraarylborates to form functionalized ketone products, e.g., I in ≤99% yields. These reactions occurred in the absence of a directing group and demonstrate esters were competent acyl electrophiles for intermol. alkene carboacylation reactions.
Organic Letters published new progress about Acid chlorides Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 17082-09-6 belongs to class chlorides-buliding-blocks, and the molecular formula is C9H7ClO, SDS of cas: 17082-09-6.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics