Mishra, Aniket; Mukherjee, Upasana; Sarkar, Writhabrata; Meduri, Sudha Lahari; Bhowmik, Arup; Deb, Indubhusan published the artcile< Diastereoselective Spirocyclization of Cyclic N-Sulfonyl Ketimines with Nitroalkenes via Iridium-Catalyzed Redox-Neutral Cascade Reaction>, Recommanded Product: (E)-1-Chloro-4-(2-nitrovinyl)benzene, the main research area is diastereoselective spirocyclization cyclic sulfonyl ketimine nitroalkene; iridium catalyst redox neutral cascade reaction.
An Ir(III)-catalyzed [3 + 2] annulation of weakly coordinating N-sulfonyl ketimines with challenging α, β-unsaturated nitro olefins has been achieved via redox-neutral C-H functionalization in the presence of a catalytic amount of silver hexafluoroantimonate. The generation of three consecutive stereogenic centers in a single step via direct C-H functionalization is the prime feature of this methodol. A wide array of pharmaceutically relevant nitro-substituted spirocyclic benzosultams was synthesized with good to excellent diastereoselectivity as well as in high yield starting from easily accessible substrates.
Organic Letters published new progress about Alkenes, nitro Role: RCT (Reactant), RACT (Reactant or Reagent) (stereoselective). 5153-70-8 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H6ClNO2, Recommanded Product: (E)-1-Chloro-4-(2-nitrovinyl)benzene.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics