Saha, Arijit; Wu, Chia-Ming; Peng, Rui; Koodali, Ranjit; Banerjee, Subhash published the artcile< Facile Synthesis of 1,3,5-Triarylbenzenes and 4-Aryl-NH-1,2,3-Triazoles Using Mesoporous Pd-MCM-41 as Reusable Catalyst>, Related Products of 5153-70-8, the main research area is triarylbenzene preparation nitrostyrene denitrative cyclotrimerization MCM41 supported palladium catalyst; triazole preparation nitrostyrene denitrative cycloaddition MCM41 supported palladium catalyst.
We report mesoporous nano-Pd-MCM-41 catalyzed rapid and efficient synthesis of 1,3,5-triarylbenzenes via de-nitrative cyclotrimerization of β-nitrostyrenes. All the reactions were very fast and high yielding. The Pd-MCM-41 was also very effective in catalyzing de-nitrative [3+2] cycloaddition of β-nitrostyrenes with TMSN3 to synthesize 4-aryl-NH-1,2,3-triazoles. The catalyst was reused at least up to eight times with min. loss of catalytic activity.
European Journal of Organic Chemistry published new progress about [3+2] Cycloaddition reaction (denitrative). 5153-70-8 belongs to class chlorides-buliding-blocks, and the molecular formula is C8H6ClNO2, Related Products of 5153-70-8.
Referemce:
Chloride – Wikipedia,
Chlorides – an overview | ScienceDirect Topics